聚酮单丝材料的渔用适配性
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S 971.1

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工信部高技术船舶科研项目 (AK190014K) ;国家自然科学基金 (31972844);国家重点研发计划 (2020YFD0900803);湛江市海洋装备和海洋生物产业揭榜挂帅制人才团队项目 (2021E05034)


Study on the suitability of polyketone monofilament material for fishing
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Semi-submersible aquaculture equipment engineering development,a high-tech ship research project of the Ministry of Industry and Information Technology;National Key R&D Program (2020YFD0900803);National Natural Science Foundation of China (31972844);Science and technology innovation and R&D project of China Shipbuilding Industry Corporation,Deep Sea Large Intelligent Breeding Equipment (201817 K).

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    摘要:

    聚酮 (POK)材料是由一氧化碳、烯烃 (乙烯、丙烯)共聚合成的一种工程塑料,有着良好的拉伸性能和抗冲击性能。为了探究POK单丝材料的渔用适配性,实验利用差示扫描量热分析仪、动态力学性能分析仪、万能拉力试验机、磨耗仪等设备对POK单丝的热性能、动态力学性能、蠕变性能、力学性能以及耐磨性能进行了测试分析。结果发现,POK单丝的结晶度为38.44%、熔融温度为200.8 ℃,且使用环境温度可达150 ℃;与相同直径的超高分子量聚乙烯 (UHMWPE)单丝和聚酰胺 (PA)单丝相比,同等温度下POK单丝的模量最大 (118.04 MPa),且在低温下 (0~20 ℃)具有更优异的力学模量;蠕变试验测得POK单丝的拉伸应变在9%左右,在绳网的长效应用上POK单丝明显优于UHMWPE单丝和PA单丝;在结节状态下,POK单丝的结节强力在干 (3.96 daN)、湿 (4.02 daN)状态下均高于同等直径的UHMWPE单丝和PA单丝;另外,POK单丝的耐磨性能表现优异,在相同摩擦条件下,干 (湿)态下POK单丝的强力保持率达58.38% (60.90%),也高于同等直径的UHMWPE单丝和PA单丝。研究表明,与相同直径的UHMWPE单丝和PA单丝相比,POK单丝耐磨性好、耐高温、高模量、低蠕变、高结节强力,其综合性能高和适配性好,这为渔用POK单丝绳索网具的开发及其产业化应用提供了理论和技术支撑。

    Abstract:

    Polyketone (POK) material is an engineering plastic copolymerized by carbon monoxide and olefins (ethylene, propylene). It has good tensile properties and excellent impact resistance, and is expected to become a new fishery material. In order to explore the suitability of POK monofilament materials for fishing, the thermal properties, dynamic mechanical properties, creep properties, mechanical properties and wear resistance of POK monofilament were comprehensively tested and analyzed by differential scanning calorimeter, dynamic mechanical properties analyzer, universal tensile testing machine, abrasion tester and other equipment. The results showed that: the crystallinity of POK monofilament is 38. 44%,the melting temperature is 200. 8 ℃, and the use environment temperature can reach 150 ℃. Compared with the UHMWPE monofilament and polyamide (PA) monofilament of the same diameter,the modulus of POK monofilament is the largest (118. 04 MPa) at the same temperature, and it also has a better mechanical modulus at low temperature (0-20 ℃). The creep test shows that the tensile strain of POK monofilament is about 9%. The advantage of POK monofilament in the long effect of rope net is obviously higher than that of UHMWPE monofilament and PA monofilament. In the knotting state, the knot breaking load of POK monofilament is higher than UHMWPE monofilament and PA monofilament of the same diameter in both dry (3. 96 daN) and wet (4. 02 daN) conditions. In addition, the wear resistance of POK monofilament is excellent. Under the same friction conditions, the rate of retention strength of POK monofilament in the dry (wet) state is 58. 38% (60. 90%), which is also higher than that of UHMWPE monofilament and PA monofilament with the same diameter. Research shows that compared with UHMWPE monofilament and PA monofilament of the same diameter, POK monofilament has abrasion resistance, high temperature resistance, high modulus, low creep, high nodular strength, and its comprehensive performance and adaptability are good,which provides theoretical and technical support for the development and industrial application of POK monofilament rope netting for fishing. With the far-reaching sea cage aquaculture, large fence aquaculture, Antarctic krill fishery and tuna seine fishery development of modern fishery, fishing fiber should possess wear resistance, anti-pollution function, degradation performance, creep resistance. In order to meet the high-quality development needs of modern fisheries, through further technical research and development, it is expected to develop new modified POK monofilament materials with antifouling function,degradation function and high strength performance in the future. Therefore, POK monofilament has a broad application prospect in fisheries, and can be used as fiber materials in fields such as deep sea cage, breeding fence, and ocean fishing gear. However, there is a long way to go and further research is needed.

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孙斌,余雯雯,石建高,王猛,徐俊杰.聚酮单丝材料的渔用适配性[J].水产学报,2022,46(11):2218~2225

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  • 收稿日期:2021-03-09
  • 最后修改日期:2021-10-28
  • 录用日期:2021-11-05
  • 在线发布日期: 2022-11-14
  • 出版日期: 2022-11-01